Specific Heat Capacities of Air

The nominal values used for air at 300 K are C P = 1.00 kJ/kg.K, C v = 0.718 kJ/kg.K,, and k = 1.4. However they are all functions of temperature, and with the extremely high temperature range experienced in internal combustion and gas turbine engines one can obtain significant errors. The table following gives the values of specific heat capacities as a function of temperature. We find that choosing values of specific heat capacities at the average temperature of each process gives results with reasonable accuracy (within around 1%).

Ideal gas specific heat capacities of air

Temperature
K

C P
kJ/kg.K

C v
kJ/kg.K

k

250

1.003

0.716

1.401

300

1.005

0.718

1.400

350

1.008

0.721

1.398

400

1.013

0.726

1.395

450

1.020

0.733

1.391

500

1.029

0.742

1.387

550

1.040

0.753

1.381

600

1.051

0.764

1.376

650

1.063

0.776

1.370

700

1.075

0.788

1.364

750

1.087

0.800

1.359

800

1.099

0.812

1.354

900

1.121

0.834

1.344

1000

1.142

0.855

1.336

1100

1.155

0.868

1.331

1200

1.173

0.886

1.324

1300

1.190

0.903

1.318

1400

1.204

0.917

1.313

1500

1.216

0.929

1.309

The values up to 1000 K were originally published in "Tables of Thermal Properties of Gases", NBS Circular 564,1955. The last five rows were calculated from a formula by B G Kyle "Chemical and Process Thermodynamics", Englewood Cliffs / Prentice Hall, 1984, and have <1% error.


Engineering Thermodynamics by Israel Urieli is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 3.0 United States License

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