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Soil pH—Glass Electrode Method

By Jared L. DeForest

Standards

  • Buffer solution 4.00 (Fisher # SB101-500)
  • Buffer solution 5.00 (Fisher # SB102-500)
  • Buffer solution 7.00 (Fisher # SB108-500)
  • Deionized (DI) water (503 Porter)

Materials

  • pH meter with glass electrode
  • 125 ml sample cup
  • Graduated cylinder (25 ml) or repipettor
  • Orbital shaker

Procedure

Add the following to 125 ml sample cup

  • 10 g Oven-dried equivalent, sieved soil (can be air dried or field fresh)
  • 20 ml Deionized (DI) water—A 1:1 dilution (10 g soil to 10 ml DI water) is also acceptable. Do not exceed a 1:5 dilution.

Place on orbital shaker (150 rpm) for 30 minutes.

Let stand for 10 minutes to equilibrate with atmospheric CO 2 and then swirl gently.

Calibrate pH meter with pH 4.0, 5.0, and 7.0 buffer solutions.

  • Note that buffer solutions are standardized to specific temperatures. You may have to adjust buffer pH when room temperature differs greatly from 25°C.

Insert pH electrode into soil slurry and read the pH after display has stabilized on a calibrated pH meter.

Rinse pH electrode with DI water to remove any soil or organic matter before moving onto next sample. Please do not blot with a tissue (i.e., Kimwipe).

Check calibration after every 15 samples to nearest pH buffer of soil pH. Recalibrate if necessary.

What to Report

  • Soil slurry dilution (1:2)
  • Water extracted (as opposed to 0.01 CaCl 2 or 1 M KCl solution)
  • Air dried or field fresh soil
  • pH units to at least 0.1

Created: 01/27/09; Revised: 10/10/11

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